Dilithium tetrachlorocuprate(II) solution
Lithium tetrachlorocuprate
CAS: 15489-27-7
Molecular Formula: Cl4CuLi2
Dilithium tetrachlorocuprate(II) solution - Names and Identifiers
Dilithium tetrachlorocuprate(II) solution - Physico-chemical Properties
| Molecular Formula | Cl4CuLi2 |
| Molar Mass | 219.24 |
| Density | 0.91g/mLat 25°C |
| Boling Point | 66°C |
| Flash Point | 1°F |
| Solubility | Difficult to mix. |
| Appearance | Liquid |
| Specific Gravity | 0.91 |
| Color | Dark orange |
| Exposure Limit | ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)OSHA: TWA 200 ppm(590 mg/m3)NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) |
| Storage Condition | Flammables area |
| Sensitive | Moisture Sensitive |
Dilithium tetrachlorocuprate(II) solution - Risk and Safety
| Risk Codes | R11 - Highly Flammable R19 - May form explosive peroxides R36/37 - Irritating to eyes and respiratory system. R40 - Limited evidence of a carcinogenic effect |
| Safety Description | S16 - Keep away from sources of ignition. S29 - Do not empty into drains. S33 - Take precautionary measures against static discharges. S46 - If swallowed, seek medical advice immediately and show this container or label. S37 - Wear suitable gloves. S36 - Wear suitable protective clothing. S13 - Keep away from food, drink and animal foodstuffs. |
| UN IDs | UN 1993 3/PG 2 |
| WGK Germany | 1 |
| FLUKA BRAND F CODES | 10-21 |
| HS Code | 28429090 |
| Hazard Class | 3 |
| Packing Group | II |
Dilithium tetrachlorocuprate(II) solution - Reference Information
| Use | Dichlorogubinic acid Chinese alias: lithium tetrachlorocubinic acid, used for Grignard reagent and bromoalkane or toluenesulfonate Cross coupling reaction. |
| Production method | 0.2 moles of lithium chloride and 0.1 moles of copper chloride are reacted in 1000 ml of tetrahydrofuran to obtain tetrahydrofuran solution of dipotassium tetrachloroate. |
Last Update：2024-04-09 02:00:04
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